Ag-Cellulose/CNT Composite for Molecular Detection

Aromatic molecules are ubiquitous environmental pollutants, which show a significant threat to human health because of their hazardous nature. Currently, many research works focus on developing rapid molecular detection techniques compared to time-consuming conventional detection methods with complicated procedures. Recently we have introduced a technique for rapid detection of phthalates in solutions in which we have used carbon nanotube (CNT) buckypapers and CNT/cellulose composite membranes as an electrochemical sensing materials. However, they have a limitation of detecting phthalates in dilute solutions, which is great disadvantage. Therefore in this study, Silver (Ag) incorporated cellulose is used with CNT to develop a highly sensitive phthalate sensing material. Based on the studies carried out so far, this developed material shows potential for detecting down to 1 ppm (v/v) concentrated phthalates in solutions. Further studies on increasing the sensitivity of the developed phthalate sensing cellulose/CNT material and developing an easy-to-use, real-time, and in-situ phthalate sensor are to be done.

 

Manuscripts:

Anuchani, P.; Abeysinghe, H.; Etampawala, T.N.B.; Ag-nanoparticle Decorated Cellulose/CNT Composite for Detection of Aromatic Molecules, MRS Advances (Submitted, 2022)

ag-cellulose

Development of 2D Piezoresistive Sensor Using CNT/Rubber Composites

Piezoresistive materials can change their resistivity with respect to the applied pressure. Therefore, piezoresistive materials are used in the development of pressure sensors. This project focuses on developing MWCNT/rubber composites as piezoresistive materials, which could use for monitoring real-time pressure. For instance real-time monitoring of the terrain that an automobile is going on, quality of gasket, the assembling faults associated with aircraft body panels etc. Ongoing studies focus on developing both active material as well as digital algorithms for capturing piezoresistive behaviors of the developed composites. Further studies are to be conducted on building a prototype 2D pressure sensor that can monitor the real-time pressure variation using a mobile device via Bluetooth or Wi-Fi technology.

 

Manuscripts:

De Silva, D.J.; Abeysinghe, H.; Etamapwala, T.N.B.; Carbon Nanotube/Rubber Composites for Pressure Sensing Applications, MRS Advances (Submitted, 2022)

Competitions:

Submitted as an innovation proposal to the ‘Invenção’, Innovative idea competition 2022 organized by the Physics Society of University of Sri Jayewardenepura

Silica embedded polymer film for the adsorption of dyes and pesticides from waste water

Industrialization has caused high water pollution with the continuous release of harmful chemicals like dyes and pesticides. The aim of this research work to produce a polymer membrane embedded with rice husk silica to filter wastewater that would retain harmful chemicals. The polymer membrane is made out of poly(vinyl alcohol) and poly ethylene glycol by embedding with the rice husk ash derived silica which is prepared using the novel method of spray drying of sodium silicate in the presence of CO2 gas. We found that the amorphous nature of the rice husk silica highly adsorb cationic dyes. However, it does not adsorb anionic dyes. This novel filtration membrane acts as a quick, cheap and as well as selective membrane in filtration harmful dyes and its potential to filter out pesticides is currently undergoing.

silica

Preparation of CNT filled NR latex Nanocomposite using Spray Dry method

Natural rubber based nanocomposites have current and potential applications in many fields. Mostly the nanomaterial are incorporated to rubber lattices during the compounding stage. However homogeneours dispersion of nanomaterial in rubber matrix is very challenging.

cnt-nr

In this research we are trying to develop a spray drying process to improve the dispersion of carbon based nano materials such as graphite and carbon nanotubes in rubber lattices. The nanomaterils is first homogenized in latex and then spray dried to get well-dispersed nanomaterils in dry rubber matrices. So far we have achieved the well dispersed graphite in spray dried NR lattice and they have been compounded to make rubber sheets.

Table 01: The mechanical performance of rubber sheets
Sample No Elongation at break (mm) Strain (%) Stress at break (N/mm2) Youngs Modulus (Pa)
Back flowed NR+Graphite 943.17 1886.3 4.239 2247.25
Sprayed NR+Graphie 937.75 1875.5 4.59 2447.34
Sprayed NR 919 1838.16 3.702 2013.97
RSS+Graphite 820 1641.9 2.959 1802.18

 

The mechanical properties of the rubber sheets made out of spray dried rubber is much better than that of the rubber sheets made out of conventional rubber compounding processes. Our ultimate goal is to develop a laboratory scale spray drying setup for spray drying latex containing nonmaterial.

Lab scale spray dryer set up
Lab scale spray dryer set up